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              IBRACON Structures and Materials Journal • 2012 • vol. 5  • nº 2
            
            
              
                E. M. R. FAIRBAIRN
              
            
            
              
                |
              
            
            
              
                T. P. DE PAULA  |
              
            
            
              
                G. C. CORDEIRO
              
            
            
              |
            
            
              
                B. B. AMERICANO
              
            
            
              |
            
            
              
                R. D. TOLEDO FILHO
              
            
            
              the set of cement/ash municipalities with greater transport distance
            
            
              between themselves, being, apparently, the less favorable scenario
            
            
              for the emissions reduction. The greatest possible distances be-
            
            
              tween the various pairs of cement/sugar cane municipalities in São
            
            
              Paulo occur between Ribeirão Pires, east of the state, with a produc-
            
            
              tion of 631 kt of cement and the cane producer municipalities of the
            
            
              west region of São Paulo. Faraway 724 km of Ribeirão Pires, the
            
            
              city of Teodoro Sampaio is the furthest from that town and presented
            
            
              a production of 897.3 kt of sugar cane, followed by Andradina and
            
            
              Pereira Barreto, with distances of 719 km and 711 km and produc-
            
            
              tions of 2,200 and 1,300 kt of sugar cane, respectively.
            
            
              The determination of the most favorable scenario for CDM de-
            
            
              ployment within the State of São Paulo would involve all possible
            
            
              combinations of additives producers and receivers as well as the
            
            
              various combinations of quantity of ash transported. The most fa-
            
            
              vorable set of combinations would be one that minimized the final
            
            
              average distance of ash transportation. This analysis has been
            
            
              addressed in recent studies of Fairbairn
            
            
              
                et al
              
            
            
              . [21], where the use
            
            
              of computational algorithms for transport distance minimization
            
            
              and for optimization of the ash distribution among the factories
            
            
              was successful.
            
            
              
                7. Results
              
            
            
              
                
                  7.1 Scenario 1: municipalities of greater  
                
              
            
            
              
                
                  production of ash and cement
                
              
            
            
              For this scenario, the calculation of emission reductions resulting
            
            
              from the implementation of CDM is done between the two munici-
            
            
              palities of greater production of the state of São Paulo: Jaboticabal
            
            
              and Sorocaba.
            
            
              The two cities are separated by a road distance of 318 km. Con-
            
            
              sidering the share of ash on the total cement produced as 7.5%
            
            
              (cement type A with 0% ash and cement type B with 15% ash) and
            
            
              the cement production of Sorocaba, 209.475 kt of ash are required
            
            
              for this scenario, which is easily supplied by the ash production
            
            
              of Jaboticabal, estimated at 790.769 kt. Table 1 summarizes the
            
            
              results obtained by applying the ACM 0005 methodology for emis-
            
            
              sions calculating in scenario 1.
            
            
              
                
                  7.2 Scenario 2: most unfavorable ash transport  
                
              
            
            
              
                
                  distances
                
              
            
            
              The scenario 2 estimates the worst-case situation for CDM project
            
            
              implementation regarding emissions from ash transport, the main
            
            
              emission arising from the use of this additive. The cement produc-
            
            
              tion of Ribeirão Pires requires, for the proposed ratio of replace-
            
            
              ment, 47.3 kt of ash. Whereas Teodoro Sampaio produces 22.4
            
            
              kt of additive, there is a deficit of -24.9 kt of ash to supply the total
            
            
              production of cement. This way, was included the production of
            
            
              55 kt of ash from Andradina, which presents the second largest
            
            
              transport distance, keeping the analysis conservative and supply-
            
            
              ing the project with surpluses of ash. It is worth to point out that
            
            
              the economic and financial feasibility of ash transportation is not
            
            
              part of the scope of this analysis, which is restricted to the criteria
            
            
              defined by the ACM 0005 methodology.
            
            
              For this scenario, the calculation of fugitive emissions for ash trans-
            
            
              port, called Leakage, and the calculation of emission reductions
            
            
              are separated into two equations: one for the transport of 22.4 kt of
            
            
              ash from Teodoro Sampaio to Ribeirão Pires, and another to 24.9
            
            
              kt transported from Andradina to the same municipality. The sum
            
            
              of the emission reductions of both alternatives make up the final
            
            
              emission reduction of the scenario 2. The results obtained for this
            
            
              scenario are shown in table 2.
            
            
              
                8. Discussion
              
            
            
              In both scenarios analyzed was possible to obtain a positive bal-
            
            
              ance of emissions reduction, revealing that there are real perspec-
            
            
              tives of CDM project implementation. Even for the scenario 2, the
            
            
              most unfavorable due to the largest transport distances, the aver-
            
            
              age CO
            
            
              2
            
            
              emissions per ton of ash (L
            
            
              add_trans
            
            
              ) is almost 100 times
            
            
              smaller than the CO
            
            
              2
            
            
              emissions per ton of clinker (
            
            
              〖
            
            
              BE/PE
            
            
              〗
            
            
              clinker
            
            
              ).
            
            
              The results obtained for CO
            
            
              2
            
            
              emissions per ton of cement on the
            
            
              Baseline of both scenarios are lower than the world average, es-
            
            
              timated at 1.0 tons of CO
            
            
              2
            
            
              per ton of cement [2]. This low rate of
            
            
              emissions is due to the fact that the energy matrix that underlies
            
            
              the Brazilian power grid is hydroelectric in nature, which emission
            
            
              factors are considerably smaller than those of other energy sourc-
            
            
              es more common in other countries. This fact is demonstrated by
            
            
              the low values of the terms
            
            
              〖
            
            
              BE
            
            
              〗
            
            
              ele_grid_clnk
            
            
              and
            
            
              〖
            
            
              PE
            
            
              〗
            
            
              ele_grid_clnk
            
            
              .
            
            
              Emissions relating to calcination reaction and the burning of fossil
            
            
              fuels represent almost all emissions of Baseline for both scenarios.
            
            
              However, among the factories considered in this study, there is a
            
            
              considerable discrepancy in relation to the use of fossil fuels in the
            
            
              production, denoting sensitive technological differences. Factories
            
            
              in the municipality of Ribeirão Pires did not register emissions re-
            
            
              lating to the combustion of fuels, unlike factories of Sorocaba.
            
            
              In both scenarios, the total amount of SCBA generated was able
            
            
              to supply the demand of factories, generating surpluses of ash.
            
            
              It is possible to imagine a series of alternatives for destination of
            
            
              this surplus as: (1) involve more cement factories and sugar cane
            
            
              mills in the project; (2) increase the fraction of ash on cement in
            
            
              the analyzed scenarios through technological improvements in the
            
            
              ash preparation and (3) increase the production of cement in the
            
            
              analyzed scenarios. All these alternatives raised could promote
            
            
              greater emission reductions.
            
            
              A more detailed study of the feasibility of implementing this type of
            
            
              CDM project should consider a financial and economic analysis,
            
            
              incorporating ash staging and obtaining costs, transport costs, the
            
            
              revenue obtained by selling the CER, besides several variables of
            
            
              the local market, but that are outside of the purposes of this work.
            
            
              However, it is noteworthy that, in the case of a residue to be dis-
            
            
              posed, the ash has a obtaining cost virtually nil, although its cost
            
            
              tends to increase with the increasing in demand. In relation to the
            
            
              revenue obtained by selling the CER, the amount paid per ton of
            
            
              CO
            
            
              2
            
            
              has historically varied between € 15 and € 35.
            
            
              
                9. Conclusions
              
            
            
              Initiatives to reduce environmental impacts in the industry as
            
            
              the reduction of greenhouse gas emission and re-use of waste
            
            
              generated are strategic, both politically and economically, and
            
            
              configure themselves as issues of great relevance in the cur-
            
            
              rent international scenario. In this sense, the use of SCBA as
            
            
              an additive in the manufacture of cement goes towards the
            
            
              global yearning for environmentally correct production technolo-
            
            
              gies. The capacity of improvement in mechanical performance