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              IBRACON Structures and Materials Journal • 2012 • vol. 5  • nº 2
            
            
              
                J. TANESI
              
            
            
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                M. G. da SILVA
              
            
            
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                V. GOMES
              
            
            
              type of structure, the reinforcement ratio, placing and consolida-
            
            
              tion. It is usually specified in terms of slump, however, in some
            
            
              cases, other requirements could be used such as slump loss over
            
            
              time, segregation and initial set, as they may directly affect the
            
            
              construction, concrete quality and its durability.
            
            
              The requirements related to structural safety also depend on the
            
            
              specific use and structure design, and among them are the com-
            
            
              pressive strength, flexural strength, modulus of elasticity and creep.
            
            
              When using mixtures with high level of supplementary cementi-
            
            
              tious materials, the 28 day compressive strength may not be a
            
            
              proper requirement, since such mixtures may develop strength
            
            
              slower than plain mixtures. In this case, a 56 or 63 day compres-
            
            
              sive strength may better represent the strength characteristics of
            
            
              these mixtures.
            
            
              
                3.2.2.2 Durability requirements
              
            
            
              Specifying durability requirements is a much more difficult task
            
            
              than specifying structural safety requirements. Those requirements
            
            
              should be selected based on the exposure class of the structure.
            
            
              Figure 2 shows the sequence for the selection of durability perfor-
            
            
              mance requirements and criteria.
            
            
              n
            
            
              
                Step 1:
              
            
            
              the owner must choose the service life. Internationally,
            
            
              some structures are already being designed for a minimum
            
            
              service life of 100 years. However, not all structures need to
            
            
              last the same period of time. Structures with higher repair and
            
            
              reconstruction costs, which may cause more disturbances to
            
            
              the environment and offer a greater risk to society typically,
            
            
              require higher service life.
            
            
              n
            
            
              
                Step 2:
              
            
            
              the owner must specify whether or not special require-
            
            
              ments are needed, such as color, texture, skid resistance,
            
            
              aesthetics, reflectance, flatness and lifecycle cost analysis,
            
            
              among others. In this stage, the owner must specify any sus-
            
            
              tainability requirement, as well. The definition of sustainability
            
            
              requirements at this stage is important because besides being
            
            
              required for the performance criteria selection (step 7), it may
            
            
              also influence the definition of exposure classes (step 4).
            
            
               In case sustainability requirements are incorporated into Bra-
            
            
              zilian specifications, it is necessary to establish performance
            
            
              indicators and tools for calculating the life-cycle inventory for
            
            
              conditions and materials available in Brazil.
            
            
              n
            
            
              
                Step 3:
              
            
            
              the structural designer must specify the structural
            
            
              safety requirements, such as compressive strength and flex-
            
            
              ural strength and modulus of elasticity, among others. In addi-
            
            
              tion, depending on the reinforcement spacing, dimensions of
            
            
              structure elements, the designer should define the slump or
            
            
              other parameter related to workability.
            
            
               In this stage, the contractor should consider construction is-
            
            
              sues related to environment, such as the temperature at the
            
            
              time of construction, and then specify any property required to
            
            
              handle slump loss, setting time and strength development.
            
            
              n
            
            
              
                Step 4:
              
            
            
              the specifier must choose the exposure classes. Sev-
            
            
              eral classes of exposure may be necessary to characterize a
            
            
              structure, because multiple mechanisms of deterioration may
            
            
              be involved, as, for example, in a structure that, in addition to
            
            
              being subject to seawater chloride induced reinforcement cor-
            
            
              rosion (class CAM), has also the risk of alkali-aggregate reac-
            
            
              tion (class E).
            
            
               If concrete with high levels of blast-furnace slag is used, which
            
            
              could potentially provide a greater susceptibility to carbonation,
            
            
              in some cases, it may be advisable to incorporate CB exposure
            
            
              class, so that any mixture used is investigated with respect to
            
            
              carbonation and, if necessary, measures are taken to prevent
            
            
              carbonation induced reinforcement corrosion.
            
            
               In addition, different parts of the structure may be subject to
            
            
              different levels of severity. For example, a bridge deck could
            
            
              be classified as CAM-1, while the columns could be classi-
            
            
              fied as CAM-3. Different subclasses, despite having the same
            
            
              performance requirements, may have very distinct perfor-
            
            
              mance criteria.
            
            
               At this point, it is important to establish the performance re-
            
            
              quirements related to durability. The requirements should be
            
            
              chosen taking into account what models will be used to predict
            
            
              the service life, because these requirements should be the in-
            
            
              puts in these models or should have a clear correlation with
            
            
              them. Furthermore, the durability requirements should be able
            
            
              to reflect the deterioration mechanisms to which the structure
            
            
              is going to be subjected to.
            
            
               The following are some of the durability requirements that
            
            
              could potentially be specified. They were divided into require-
            
            
              ments related to seawater chloride induced corrosion, carbon-
            
            
              ation induced corrosion, general and special requirement
            
            
              
                3.2.2.2.1 Discussion on possible requirements related
              
            
            
              
                to chloride induced corrosion
              
            
            
              n
            
            
              
                Apparent chloride diffusion coefficient
              
            
            
              – this is one of the
            
            
              most important durability requirements as it has a direct rela-
            
            
              tionship with the ingress of chlorides and thus with reinforce-
            
            
              ment corrosion. Most mathematical models for the service life
            
            
              prediction, when considering chloride induced corrosion, use
            
            
              the diffusion coefficient as one of its inputs.
            
            
               The test used to determine this coefficient is the ASTM C 1556-
            
            
              04 (ASTM [14]) (Chloride bulk diffusion test). This test takes
            
            
              approximately three months and is relatively difficult to be car-
            
            
              ried out. Grinding 1-2 mm layers of concrete is a very delicate
            
            
              task that can lead to a high variability of test results. So, it is
            
            
              necessary to develop another test that can give an indication of
            
            
              the diffusion coefficient.
            
            
               The rapid migration test NT Build 492: 1999 (NORDEST [15])
            
            
              was developed based on the research of Tang and Nilsson [16]
            
            
              and presents an equation for calculating the chloride migration
            
            
              coefficient, which is commonly used as diffusion coefficient.
            
            
              However, the coefficient calculated on the basis of this standard
            
            
              is not the apparent diffusion coefficient used by most mathemati-
            
            
              cal models. In reality, this coefficient is not even the chloride
            
            
              diffusion coefficient but an approximation. This is because dif-
            
            
              fusion is the movement of ions due to a concentration gradient
            
            
              or chemical potential, while the migration test actually measures
            
            
              the movement of ions under an external electric field.
            
            
               If the diffusion coefficient is chosen as a requirement, it is rec-
            
            
              ommended that models, such as Life-365, are used to estimate
            
            
              the maximum acceptable diffusion coefficient for the specific
            
            
              conditions of the structure under study that would guarantee
            
            
              that the desired service life is achieved. Selected mixtures
            
            
              should be tested and should comply with these limits.
            
            
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                Total charge
              
            
            
              – ASTM C 1202-05 (ASTM [17]) is the most
            
            
              widely durability requirement used in hybrid specifications. This